Fundamental features of mesoporous functional materials influencing the efficiency of removal of VOCs from aqueous systems: A review.

Volatile organic compounds (VOCs) are harmful contaminants that are emitted into the environment as a result of various commercial, industrial, and domestic practices. Their presence in water leads to pollution and poses a huge threat to the ecological environment and human health. They are typically released into the environment through a spill or inappropriate disposal which allows the chemicals to get absorbed into the ground or enter the sewage system. Thus far, several treatment methods have been developed to remove VOCs from water, including steam stripping or air stripping, ion exchange, filtration, adsorption, and application of various types of sorbents. Due to their cost-effectiveness and efficiency, the use of mesoporous materials, especially those synthesized from coal fly ash (FA), is recognized as the most promising strategy for slowing down the impact of VOCs. This study is believed to be the first to assess the advances made in improving the adsorption of VOCs by different functional mesoporous materials (FA, zeolites, mesoporous silica, metal organic frameworks). The impact associated with the properties of these materials is carefully summarized in this paper, in regard to their solid-state characteristics, material synthesis method, and surface modification. In addition, their chemical and physical interactions in solution, the reaction kinetics, and the influence of temperature and pH are described in detail. The aim of this work was to compare the sorption properties of the materials synthesized from FA with more complex mesoporous materials. This overview provides a comprehensive understanding of VOC removal from water systems using various functional materials, as well as helps in identifying the materials that may play a key role in the future.

Synthesis and Characterization of Zeolites Produced from Low-Quality Coal Fly Ash and Wet Flue Gas Desulphurization Wastewater.

This study investigated a low-energy-consuming procedure for the synthesis of zeolite materials from coal fly ash (CFA). Materials containing zeolite phases, namely Na-X, Na-P1, and zeolite A, were produced from F-class fly ash, using NaOH dissolved in distilled water or in wastewater obtained from the wet flue gas desulphurization process, under atmospheric pressure at a temperature below 70 °C. The influence of temperature, exposure time, and alkaline solution concentration on the synthesized materials was tested. In addition, chemical, mineralogical, and textural properties of the obtained materials were determined by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and cation exchange capacity (CEC). Cd(II), Ni(II), NH4+ cation, and Se(VI) anion sorption experiments were conducted to compare the sorption properties of the produced synthetic zeolites with those of the commercially available ones. Zeolitization resulted in an increase of CEC (up to 30 meq/100 g) compared to raw CFA and enhanced the ability of the material to adsorb the chosen ions. The obtained synthetic zeolites showed comparable or greater sorption properties than natural clinoptilolite and synthetic Na-P1. They were also capable of simultaneously removing cationic and anionic compounds. The structural, morphological, and textural properties of the final product indicated that it could potentially be used as an adsorbent for various types of environmental pollutants.

Sorption of Molybdates and Tungstates on Functionalized Montmorillonites: Structural and Textural Features.

Montmorillonite-the most popular mineral of the smectite group-has been recognized as a low-cost, easily available mineral sorbent of heavy metals and other organic and inorganic compounds that pollute water. The aim of this work was to determine the sorption mechanism and to identify the reaction products formed on the surface of montmorillonite and organo-montmorillonite after sorption of molybdates (Mo(VI)) and tungstates (W(VI)). Montmorillonites are often modified to generate a negative charge on the surface. The main objective of the study was to investigate and compare the features of Na-montmorillonite (Na-M), montmorillonite modified with dodecyl trimethyl ammonium bromide (DDTMA-M), and montmorillonite modified with didodecyl dimethyl ammonium bromide (DDDDMA-M) before and after sorption experiments. The material obtained after sorption was studied by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The XRD pattern showed the presence of a new crystallic phase in the sample that was observed under an SEM as an accumulation of crystals. The FTIR spectra showed bands related to Mo-O and W-O vibration (840 and 940 cm-1, respectively). The obtained results suggest that molybdenum(VI) and tungsten(VI) ions sorb onto the organo-montmorillonite in the form of alkylammonium molybdates and tungstates.